First substoichiometric version of the catalytic enantioselective addition of an alkyllithium to an aldehyde.
نویسندگان
چکیده
A substoichiometric enantioselective version of the extremely fast nucleophilic addition of Alk-Li to RCHO is made possible thanks to a thorough analysis of the aggregation phenomena involved in the reaction: calculated quantities of LiCl must be added to the medium at the right time to keep the catalytic cycle running.
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 35 شماره
صفحات -
تاریخ انتشار 2011